Sulphate contributions to PM10 aerosol sampled at Gruvebadet Observatory (Ny-Ålesund)

Main a trace chemical markers annually and seasonally averaged concentrations in the aerosol (bulk and PM10) sampled in 10 sites in the Arctic and Panarctic regions

Measurement of the concentration and turbulent flux of CO2 and CH4 at 15 m above sea level on the CCT.

Aerosol Biogeochemical cycles, Sources and TRansport processes in the climate-sensitive ArCTic - ABSTRACT Dataset consists in: Aerosol load, Ion, metal, EC/OC measurements on bulk and size-segregated particulate matter at Gruvebadet Observatory (Ny Alesund - Italian Station "Dirigibile Italia") using Aerosol sampling and measurement devices (TECORA ECHO-PM, TECORA Skypost, TECORA HI-VOL, FAI PBL, TSI SMPS, TSI APS - Ion Chromatographs, ICP-AES, Thermo-Optical Analyzer, ICP-MS) Aerosol measurements and sampling. Atmospheric Particle Size Distribution. SMPS (10-500 nm) and APS (0.5-20 um). PM10 aerosol low volume sampling for determination of ions and metals: continuous 24/48h resolution samplings. Multi-stage impactor (Dekati 4-stage: < 1 um - > 10 um) for measurement of ion composition: 4-day resolution sampling. PM10 medium volume sampling for determination of metal content and Pb isotope ratios: 4-d resolution samplings. PM10 on quartz filters for determination of Elemental od Organic Carbon (EC/OC): continuous 24/48 h resolution samplings. PM10 aerosol low volume sampling on PTFE for elemental determination by PIXE technique.

Activities: - PM1 sampling by a High-Volume Sampler (TECORA eco-highvol equipped with digital PM1 sampling inlet, nominal flow 500 lpm) on pre-washed and pre-baked quartz-fiber filters (PALL, Ø= 18cm). Sampling time: 3-4 days per sample. - Off-line filter based AMS characterization of water soluble non-refractory sulfate, nitrate, ammonium, chloride, and organic mass (NR-PM1). - Off-line filter-based spectroscopic characterization of the water-soluble organic mass in term of chemical functional groups and specific markers by means of proton-Nuclear Magnetic Resonance spectroscopy (H-NMR). - Source apportionment of organic aerosol by means of multivariate statistical techniques (namely Positive Matrix Factorization, PMF, and other factor analysis methods) applied on both AMS and NMR spectral datasets. Available data: -NMR functional groups (Aromatics, anomeric/vynilic, H-C-O, H-C-C=, H-C) -NMR tracers: Levoglucosan, Methane-sulphonic acid (MSA), Hydroxymethane-sulphonic acid (HMSA), Amines (mono-, di- and tri-methyl amines, etc.) -HR-TOF-AMS (off-line): main species (Org, SO4, NO3, NH4, Chl), elemental ratios (OM:OC, O:C, H:C) & tracer fragments (m/z43, 44, 60 etc.) -NMR & AMS OA source apportionment

Aerosol sampling by a High-Volume Sampler (TECORA eco-highvol equipped with digital PM1 sampling inlet, nominal flow 500 lpm) for the collection of ambient aerosol particles with aerodynamic diameter < 1 μm (PM1) on pre-washed and pre-baked quartz-fiber filters (PALL, Ø= 18cm). Sampling time: 3-4 days per sample. A multi-technique analytical approach for the characterization of the sampled organic aerosol: Organic matter (OM) and Organic Nitrogen (ON). Analytical techniques employed are based on nuclear magnetic resonance spectroscopy (NMR) and Aerosol Mass Spectrometry (HR-TOF-AMS applied off-line) for the OM characterization, C and N elemental analysis (CN-EA) and ion chromatography (IC) for inorganic ions and alkyl-amines. -NMR functional groups (Aromatics, anomeric/vynilic, H-C-O, H-C-C=, H.C) -NMR tracers: Levoglucosan, Methane-sulphonic acid (MSA), Hydroxymethane-sulphonic acid (HMSA), Amines (mono-, di- and tri-methyl amines, etc.) -HR-TOF-AMS (off-line): main species (Org, SO4, NO3, NH4, Chl), elemental ratios (OM:OC, O:C, H:C) & tracer fragments (m/z43, 44, 60 etc.) -NMR & AMS OA source apportionment