Ice Nuclei Particle Concentration (INPAIR) INPAIR Svalbard' Chemistry and Physics of the Atmosphere: Ice nucleating particle (INPs) concentration obtained in spring and summer campaigns in the Arctic Region. Measurements of INPs concentrations and activation fraction of aerosol in Arctic (e.g. Gruvebadet observatory in Ny-Ãlesund). b) Correlating INPs concentration with meteorological parameters and physicochemical characterisations. Instrument: PM1 and PM10 sampling lines. DFPC chamber

Monitoring of Aerosol: Short and Long range source areas related to Climate Change (MAShLoCC) During the Arctic campaign 2010, an atmospheric aerosol sampling at the Gruvebadet observatory has been carried out in order to obtain information about the formation and composition of atmospheric aerosol, transport processes toward the Arctic zone as well as local and remote source areas. Instrument : ICP-SFMS, IRMS, Orbitrap

Aerosol size distribution (>500 nm) measured by a SMPS 3321 (TSI).

Aerosol size distribution (10-500 nm) measured by a APS 3321

Sulphate contributions to PM10 aerosol sampled at Gruvebadet Observatory (Ny-Ålesund)

Aerosol sampling by a High-Volume Sampler (TECORA eco-highvol equipped with digital PM1 sampling inlet, nominal flow 500 lpm) for the collection of ambient aerosol particles with aerodynamic diameter < 1 μm (PM1) on pre-washed and pre-baked quartz-fiber filters (PALL, Ø= 18cm). Sampling time: 3-4 days per sample. A multi-technique analytical approach for the characterization of the sampled organic aerosol: Organic matter (OM) and Organic Nitrogen (ON). Analytical techniques employed are based on nuclear magnetic resonance spectroscopy (NMR) and Aerosol Mass Spectrometry (HR-TOF-AMS applied off-line) for the OM characterization, C and N elemental analysis (CN-EA) and ion chromatography (IC) for inorganic ions and alkyl-amines. -NMR functional groups (Aromatics, anomeric/vynilic, H-C-O, H-C-C=, H.C) -NMR tracers: Levoglucosan, Methane-sulphonic acid (MSA), Hydroxymethane-sulphonic acid (HMSA), Amines (mono-, di- and tri-methyl amines, etc.) -HR-TOF-AMS (off-line): main species (Org, SO4, NO3, NH4, Chl), elemental ratios (OM:OC, O:C, H:C) & tracer fragments (m/z43, 44, 60 etc.) -NMR & AMS OA source apportionment

Aerosol Flux in Arctic (ALFA) Evaluate aerosol dry deposition/emission in the Arctic on icy/snowy surface and its dependence on particle size and micrometeorological parameters. The measures of the particles exchange rate will be carried out with the technique of eddy-correlation at Ny Alesund in size-segregated mode (2-3000 nm) coupling a sonic anemometer, a CPC and an optical particle counter (OPC) that are able to detect fluctuations of the particles concentration at high frequency (1Hz).

Activities: - PM1 sampling by a High-Volume Sampler (TECORA eco-highvol equipped with digital PM1 sampling inlet, nominal flow 500 lpm) on pre-washed and pre-baked quartz-fiber filters (PALL, Ø= 18cm). Sampling time: 3-4 days per sample. - Off-line filter based AMS characterization of water soluble non-refractory sulfate, nitrate, ammonium, chloride, and organic mass (NR-PM1). - Off-line filter-based spectroscopic characterization of the water-soluble organic mass in term of chemical functional groups and specific markers by means of proton-Nuclear Magnetic Resonance spectroscopy (H-NMR). - Source apportionment of organic aerosol by means of multivariate statistical techniques (namely Positive Matrix Factorization, PMF, and other factor analysis methods) applied on both AMS and NMR spectral datasets. Available data: -NMR functional groups (Aromatics, anomeric/vynilic, H-C-O, H-C-C=, H-C) -NMR tracers: Levoglucosan, Methane-sulphonic acid (MSA), Hydroxymethane-sulphonic acid (HMSA), Amines (mono-, di- and tri-methyl amines, etc.) -HR-TOF-AMS (off-line): main species (Org, SO4, NO3, NH4, Chl), elemental ratios (OM:OC, O:C, H:C) & tracer fragments (m/z43, 44, 60 etc.) -NMR & AMS OA source apportionment

Aerosol absorption coefficient at 3 wavelengths (470, 530, 670 nm) measured using a Particle Soot Absorption Photometer (PSAP), manufactured by Radiance Research.

Aerosol scattering at 1 wavelength (530 nm) measured using a nephelometer M903, manufactured by Radiance Research.